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If you have an U.S. model, you can sign on your vehicle at www.mbusa.com and they may have a manual for you to download, free. (I've signed on my car, 2001 CLK430 and they have free manual for download)
I couldn't find one to download, but I bought a used 2000 S430 manual off the internet for about $40. Search google for your year/model and you should find a number of people selling them.
Buying the actual manual is probably better than a download, anyway, because you can keep it with you in the car.
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